Bücher der Reihe Nato Science Series E:

Chemical reactor engineering, as a discipline, has a central role to play in helping with the development of adequate strategies and technologies that can deal effectively with the concerns of today's society, which are increasingly becoming attuned to the environment. The current challenge is how to adapt present processes and products to meet more rigorous environmental standards. Chemical Reactor Technology for Environmentally Safe Reactors and Products addresses these issues in three parts: I -- Fuels of the Future and Changing Fuel Needs; II -- Alternative Sources; III -- Emission Control, Chemical Reactor Safety and Engineering. Attention is also paid, throughout the text, to the fundamental technological aspects of reactor engineering and to possible strategies for bridging knowledge gaps.

In this volume is presented the proceedings of a NATO Advanced Study Institute (ASI) on the theme of Electromagnetic Modelling and Measurements for Analysis and Synthesis Problems. The ASI was held at 11 Ciocco, Castelvecchio Pascoli, Tuscany, Italy, August 10th - 21st, 1987. It has been my good fortune to act as co-director of two of Jozef's previous ASIs, and so I am well acquainted with the JKS format for ASIs. As participants will realise, I did not attend this ASI, and so I only have a partial appreciation of the programme. In particular it has not been possible to include transcripts of any panel discussions which may have taken place. Readers may recall that such transcripts have formed a most interesting and useful part of previous ASI proceedings edited by Jozef Skwirzynski, and helped to convey the spirit of the meetings. Unfortunately it has proved impossible to locate the tapes, despite the best efforts of Jozef's assistant, Barry Stuart. A further dificulty has arisen through the untimely death of Jozef's former deputy and colleague at GEC Research, Ed Pacello, who assisted Jozef with the organisation of the precursor of this ASI. The following is taken from original material relating to the aims of the Advanced Study Institute: "e;PURPOSE OF THE INSTITUTE This Institute is concerned with computer modelling and with experimental measurements as two complementary tools for both analysis and synthesis of electromagnetics (EM), infra-red (IR) and optical problems.

Supercritical fluids are neither gas nor liquid, but can be compressed gradually from low to high density and they are therefore interesting and important as tunable solvents and reaction media in the chemical process industry. By adjusting the density the properties of these fluids can be customised and manipulated for a given process - physical or chemical transformation. Separation and processing using supercritical solvents such as CO2 are currently on-line commercially in the food, essential oils and polymer industries. Many agencies and industries are considering the use of supercritical water for waste remediation. Supercritical fluid chromatography represents another, major analytical application. Significant advances have recently been made in materials processing, ranging from particle formation to the creation of porous materials.The chapters in this book provide tutorial accounts of topical areas centred around: (1) phase equilibria, thermodynamics and equations of state; (2) critical behaviour, crossover effects; (3) transport and interfacial properties; (4) molecular modelling, computer simulation; (5) reactions, spectroscopy; (6) phase separation kinetics; (7) extractions; (8) applications to polymers, pharmaceuticals, natural materials and chromatography; (9) process scale-up.

Recent years have witnessed a resurgence in the kinetic approach to dynamic many-body problems. Modern kinetic theory offers a unifying theoretical framework within which a great variety of seemingly unrelated systems can be explored in a coherent way. Kinetic methods are currently being applied in such areas as the dynamics of colloidal suspensions, granular material flow, electron transport in mesoscopic systems, the calculation of Lyapunov exponents and other properties of classical many-body systems characterised by chaotic behaviour. The present work focuses on Brownian motion, dynamical systems, granular flows, and quantum kinetic theory.

Micro/nanotribology as a field is concerned with experimental and theoretical investigations of processes ranging from atomic and molecular scales to the microscale, occurring during adhesion, friction, wear, and thin-film lubrication at sliding surfaces. As a field it is truly interdisciplinary, but this confronts the would-be entrant with the difficulty of becoming familiar with the basic theories and applications: the area is not covered in any undergraduate or graduate scientific curriculum. The present work commences with a history of tribology and micro/nanotribology, followed by discussions of instrumentation, basic theories of friction, wear and lubrication on nano- to microscales, and their industrial applications. A variety of research instruments are covered, including a variety of scanning probe microscopes and surface force apparatus. Experimental research and modelling are expertly dealt with, the emphasis throughout being applied aspects.

Interest in the study of early European cultures is growing. These cultures have left us objects made of gold, other metals and ceramics. The advent of metal detectors, coupled with improved analytical techniques, has increased the number of findings of such objects enormously. Gold was used for economic and ceremonial purposes and thus the gold objects are an important key to our understanding of the social and political structures, as well as the technological achievements, of Bronze and Iron Age European societies. A correct interpretation of the information provided by gold and other metal objects requires the cooperation of experts in the fields of social, materials and natural science. Detailed investigation of gold deposits in Europe have revealed the composition and genesis of the deposits as sources of the metal. In Prehistoric Gold in Europe, a group of leading European geoscientists, metallurgists and archaeologists discuss the techniques of gold mining and metallurgy, the socioeconomic importance of gold as coinage and a symbol of wealth and status, and as an indicator of religious habits, as well as a mirror of trade and cultural relations mirrored by the distribution and types of gold objects in prehistoric times.

It is widely recognized that an understanding of the optical pro- perties of matter will give a great deal of important information re- levant to the fundamental physical properties. This is especially true in semiconductor physics for which, due to the intrinsic low screening of these materials, the optical response is quite rich. Their spectra reflect indeed as well electronic as spin or phonon transitions. This is also in the semiconductor field that artificial structures have been recently developed, showing for the first time specific physical properties related to the low dimentionality of the electronic and vi- bronic properties : with this respect the quantum and fractional quan- tum Hall effects are among the most well known aspects. The associated reduced screening is also a clear manifestation of these aspects and as such favors new optical properties or at least significantly enhan- ces some of them. For all these reasons, it appeared necessary to try to review in a global way what the optical investigation has brought today about the understanding of the physics of semiconductors. This volume collects the papers presented at the NATO Advanced study Inst i tut e on "e;Optical Properties of Semiconductors"e; held at the Ettore Majorana Centre, Erice, Sicily on March 9th to 20th, 1992. This school brought together 70 scientists active in research related to optical properties of semiconductors. There were 12 lecturers who pro- vided the main contributions .

Recent developments in advanced ceramics are critically evaluated in respect to their thermal shock and thermal fatigue behavior from an interdisciplinary viewpoint by leading experts. The book covers the aspects of material development, mechanical and fracture mechanical models and experimental testing methods. Special emphasis is given to the influence of a rising crack resistance on the thermal shock behavior, novel irradiation testing methods for a quantitative characterization of the thermal shock and fatigue loading as well as detailed fracture mechanical models for single and multiple crack propagation. This book summarizes developments of the last decade concerning the thermal shock and thermal fatigue behavior of advanced ceramics. The scientific articles of the book were carefully arranged in order to achieve a textbook-like form which will be of great value to researchers and students. (ABSTRACT) This book summarizes developments of the last decade concerning the thermal shock and thermal fatigue behavior of advanced ceramics. The book covers the aspects of material development, mechanical and fracture mechanical models and testing methods. The scientific articles were carefully arranged in order to achieve a textbook-like form which will be of great value to researchers and students.

Success in the fabrication of structures at the nanometer length scale has opened up a new horizon to condensed matter physics: the study of quantum phenomena in confined boxes, wires, rings, etc. A new class of electronic devices based on this physics has been proposed, with the promise of a new functionality for ultrafast and/or ultradense electronic circuits. Such applications demand highly sophisticated fabrication techniques, the crucial one being lithography. Nanolithography contains updated reviews by major experts on the well established techniques -- electron beam lithography (EBL), X-ray lithography (XRL), ion beam lithography (IBL) -- as well as on emergent techniques, such as scanning tunnelling lithography (STL).

Nanoscale Probes of the Solid--Liquid Interface deals with the use of the scanning tunnelling microscope (STM) and related instrumentation to examine the phenomena occurring at the interface between solid and liquid. Scanning probe microscopy (the collective term for such instruments as the STM, the atomic force microscope and related instrumentation) allows detailed, real space atomic or lattice scale insight into surface structures, information which is ideally correlated with surface reactivity. The use of SPM methods is not restricted to ultrahigh vacuum: the STM and AFM have been used on samples immersed in solution or in ambient air, thus permitting a study of environmental effects on surfaces. At the solid--liquid interface the reactivity derives precisely from the presence of the solution and, in many cases, the application of an external potential. Topics covered in the present volume include: the advantages of studying the solid--liquid interface and the obtaining of additional information from probe measurements; interrelationships between probe tip, the interface and the tunnelling process; STM measurements on semiconductor surfaces; the scanning electrochemical microscope, AFM and the solid--liquid interface; surface X-ray scattering; cluster formation on graphite electrodes; Cu deposition on Au surfaces; macroscopic events following Cu deposition; deposition of small metallic clusters on carbon; overpotential deposition of metals; underpotential deposition; STM on nanoscale ceramic superlattices; reconstruction events on Au(ijk) surfaces; Au surface reconstructions; friction force measurements on graphite steps under potential control; and the biocompatibility of materials.

The development of advanced materials with preselected properties is one of the main goals of materials research. Of especial interest are electronics, high-temperature and supemard materials for various applications, as well as alloys with improved wear, corrosion and mechanical resistance properties. The technical challenge connected with the production of these materials is not only associated with the development of new specialised preparation techniques but also with quality control. The energetic charged particle, electron and photon beams offer the possibility of modifying the properties of the near-surface regions of materials without seriously affecting their bulk, and provide unique analytical tools for testing their qUality. This volume includes most of the lectures and contributions delivered at the NATO-funded Advanced Study Institute "e;Application of Particle and Laser Beams in Materials Technology"e;, which was held in Kallithea, Chalkidiki, in Northern Greece, from the 8th to the 21st of May, 1994 and attended by 73 participants from 21 countries. The aim of this ASI was to provide to the participants an overview of this rapidly expanding field. Fundamental aspects concerning the interactions and collisions on atomic, nuclear and solid state scale were presented in a didactic way, along with the application of a variety of techniques for the solution of problems ranging from the development of electronics materials to corrosion research and from archaeometry to environmental protection.

The re-emergent field of quantitative electron crystallography is described by some of its most eminent practitioners. They describe the theoretical framework for electron scattering, specimen preparation, experimental techniques for optimum data collection, the methodology of structure analysis and refinement, and a range of applications to inorganic materials (including minerals), linear polymers, small organic molecules (including those used in nonlinear optical devices), incommensurately modulated structures (including superconductors), alloys, and integral membrane proteins. The connection between electron crystallography and X-ray crystallography is clearly defined, especially in the utilisation of the latest methods for direct determination of crystallographic phases, as well as the unique role of image analysis of high-resolution electron micrographs for phase determination. Even the aspect of multiple beam dynamic diffraction (once dreaded because it was thought to preclude ab initio analysis) is considered as a beneficial aid for symmetry determination as well as the elucidation of crystallographic phases, and as a criterion for monitoring the progress of structure refinement. Whereas other texts have hitherto preferentially dealt with the analysis of electron diffraction and image data from thin organic materials, this work discusses - with considerable optimism - the prospects of looking at `harder' materials, composed of heavier atoms. Audience: Could be used with profit as a graduate-level course on electron crystallography. Researchers in the area will find a statement of current progress in the field.

This book contains the majority of the papers presented at the NATO Ad- vanced Research Workshop (ARW) held in Burlington, Vermont, USA on October 12-15, 1992. This ARW was the first of its kind to address the subject of intrinsically conducting polymers with an emphasis on processing and technological applications. The NATO ARW format was followed in that the subjects addressed here were limited in number but discussed in detail with the attendance being limited to a small number of selected scientists. The ARW brought together lecturers who are leaders in their respective fields from a wide range of NATO and non-NATO countries (a total of 11 countries) with the support of the NATO Scientific Affairs Division and some support from Champlain Cable Corporation. The total number of par- ticipants was 33 and the number of presentations was 24. The speakers were chosen based on the topics selected for this workshop and repre- sented industry, universities and government laboratories. The field of conducting polymers has grown rapidly during the past few years with important developments in materials processing and fabrica- tion that brought about active research programs focusing on the use of these polymers as "e;smart"e; materials in technological applications and devices in academic and industrial research laboratories.

The main motivation for the organization of the Advanced Research Workshop in Belgirate was the promotion of discussions on the most recent issues and the future perspectives in the field of Solid State lonics. The location was chosen on purpose since Belgirate was the place were twenty years ago, also then under the sponsorship of NATO, the very first international meeting on this important and interdisciplinary field took place. That meeting was named "e;Fast Ion Transport in Solids"e; and gathered virtually everybody at that time having been active in any aspect of motion of ions in solids. The original Belgirate Meeting made for the first time visible the technological potential related to the phenomenon of the fast ionic transport in solids and, accordingly, the field was given the name "e;Solid State lonics"e;. This field is now expanded to cover a wide range of technologies which includes chemical sensors for environmental and process control, electrochromic windows, mirrors and displays, fuel cells, high performance rechargeable batteries for stationary applications and electrotraction, chemotronics, semiconductor ionics, water electrolysis cells for hydrogen economy and other applications. The main idea for holding an anniversary meeting was that of discussing the most recent issues and the future perspectives of Solid State lonics just twenty years after it has started at the same location on the lake Maggiore in North Italy.

Sensors and Sensory Systems for an Electronic Nose reviews the current state of progress in the development of an electronic instrument capable of olfaction. The instrument -- the so-called electronic nose -- has enormous potential for application in such areas as product flavor control and environmental monitoring. The book discusses the essential elements of an electronic nose, such as chemical sensors, signal processing, and pattern recoginiton techniques. It is also one of the first contributions to the new and exciting field of machine olfaction.

Among the many intense light sources, excimer lasers have a unique set of properties that place them at the forefront of tooling for material processing. Their extreme versatility means that they can be used in many areas of materials science and medicine. But three conditions need to be fulfilled in order that their versatility be truly appreciated and exploited: the characteristics and limitations of the sources must be known; the basic excimer laser processes should become reasonably widely known; and problems in search of a solution should be clearly identified. Excimer Lasers covers all three of these points in an instructive and logical way. Probably for the first time, both instrumental and fundamental aspects of excimer laser interaction with matter are presented side-by-side, with examples drawn from the widest range of materials. The articles gathered here are tutorial in their nature, thus making them suitable for a wide readership, from recent graduates and postgraduate students to those established scientists entering the field, all of whom could not find a better, nor more authoritative work with which to start their reading.

Irrigated agriculture and the use of water resources in agriculture face the challenges of sustainable development. Research has advanced our knowledge of water use by crops, soil-water-solutes interactions, and the engineering and managerial tools needed to mobilize, convey, distribute, control and apply water for agricultural production. However, the achievements booked in user practice have revealed the need for new developments in the areas of resource conservation, control of environmental and health impacts, modernisation of technologies and management, economic viability and the social acceptance of changes. The contributions to Sustainability of Irrigated Agriculture cover most of the relevant disciplines. Besides its multidisciplinarity, the different origins, experience, backgrounds and practices of the authors provide a wide, in-depth analysis of the various aspects of water resource utilization in agriculture. The papers review scientific, technical and managerial aspects, highlighting the main problems, issues and future developments. The book covers the different aspects of sustainability, including environmental, technical, economic, institutional and social ones. Advances in irrigation science and engineering are dealt with, both on- and off-farm. Special attention is paid to the different components of water quality management, to the transfer of technology, and to capacity building.

Heterogeneous catalysis provides the backbone of the world's chemical and oil industries. The innate complexity of practical catalytic systems suggests that useful progress should be achievable by investigating key aspects of catalysis by experimental studies on idealised model systems. Thin films and supported clusters are two promising types of model system that can be used for this purpose, since they mimic important aspects of the properties of practical dispersed catalysts. Similarly, appropriate theoretical studies of chemisorption and surface reaction clusters or extended slab systems can provide valuable information on the factors that underlie bonding and catalytic activity. This volume describes such experimental and theoretical approaches to the surface chemistry and catalytic behaviour of metals, metal oxides and metal/metal oxide systems. An introduction to the principles and main themes of heterogeneous catalysis is followed by detailed accounts of the application of modern experimental and theoretical techniques to fundamental problems. The application of advanced experimental methods is complemented by a full description of theoretical procedures, including Hartree-Fock, density functional and similar techniques. The relative merits of the various approaches are considered and directions for future progress are indicated.

Ongoing developments in nanofabrication technology and the availability of novel materials have led to the emergence and evolution of new topics for mesoscopic research, including scanning-tunnelling microscopic studies of few-atom metallic clusters, discrete energy level spectroscopy, the prediction of Kondo-type physics in the transport properties of quantum dots, time dependent effects, and the properties of interacting systems, e.g. of Luttinger liquids. The overall understanding of each of these areas is still incomplete; nevertheless, with the foundations laid by studies in the more traditional systems there is no doubt that these new areas will advance mesoscopic electron transport to a new phenomenological level, both experimentally and theoretically. Mesoscopic Electron Transport highlights selected areas in the field, provides a comprehensive review of such systems, and also serves as an introduction to the new and developing areas of mesoscopic electron transport.