Bücher der Reihe Reviews in Mineralogy & Geochemistry

Volume 3 of Reviews in Mineralogy provides an up-to-date review of the mineralogy and petrology of rock-forming opaque oxide minerals. It was the textbook for the short course on rock-forming oxide minerals sponsored by the Mineralogical Society of America at the Colorado School of Mines, November 5-7, 1976. The contributors hope that the work will be valuable not only to participants in the short course, but also to others desiring a modern review of the subject.

Volume 17 of Reviews in Mineralogy is based on a short course, entitled "Thermodynamic Modeling of Geological Materials: Minerals, Fluids amd Melts," October 22-25, 1987, at the Wickenburg Inn near Phoenix, Arizona. Contents:Thermodynamic Analysis of Phase Equilibria in Simple Mineral SystemsModels of Crystalline solutionsThermodynamics of Multicomponent Systems Containing Several Solid SolutionsThermodynamic Model for Aqueous Solutions of Liquid-like DensityModels of Mineral Solubility in Concentrated Brines with Application to Field ObservationsCalculation of the Thermodynamic Properties of Aqueous Species and the Solubilities of Minerals in Supercritical Electrolyte SolutionsIgneous FluidsOre Fluids: Magmatic to SupergeneThermodynamic Models of Molecular Fluids at the Elevated Pressures and Temperatures of Crustal MetamorphismMineral Solubilities and Speciation in Supercritical Metamorphic FluidsDevelopment of Models for Multicomponent Melts: Analysis of Synthetic SystemsModeling Magmatic Systems: Thermodynamic RelationsModeling Magmatic Systems: Petrologic Applications

Volume 16 of Reviews in Mineralogy inroduces to high-temperature stable isotope geochemistry and should provide an entry into the pertinent literature, as well as some understanding of the basic concepts and potential applications.The first three chapters focus on the theory and experimental data base for equilibrium, disequilibrium, and kinetics of stable isotope exchange reactions among geologically important minerals and fluids. The fourth chapter discusses the primordial oxygen isotope variations in the solar system prior to formation of the Earth, along with a discussion of isotopic anomalies in meteorites. The fifth chapter discusses isotopic variations in the Earth's mantle and the sixth chapter reviews the variations in the isotopic compositions of natural waters on our planet. In Chapters 7, 8, 9 and 10, these isotopic constraints and concepts are applied to various facets of the origin and evolution of igneous rocks, bringing in much material on radiogenic isotopes as well, because these problems require a multi-dimensional attack for their solution. In Chapters 11 and 12, the problems of hydrothermal alteration by meteoric waters and ocean water are considered, together with discussions of the physics and chemistry of hydrothermal systems and the 18O/16O history of ocean water. Finally, in Chapters 13 and 14, these concepts are applied to problems of metamorphic petrology and ore deposits, particularly with respect to the origins of the fluids involved in those processes.

Volume 15 of Reviews in Mineralogy is written with two goals in mind. The first is to derive the 32 crystallographic point groups, the 14 Bravais lattice types and the 230 crystallographic space group types. The second is to develop the mathematical tools necessary for these derivations in such a manner as to lay the mathematical foundation needed to solve numerous basic problems in crystallography and to avoid extraneous discourses. To demonstrate how these tools can be employed, a large number of examples are solved and problems are given. The book is, by and large, self-contained. In particular, topics usually omitted from the traditional courses in mathematics that are essential to the study of crystallography are discussed. For example, the techniques needed to work in vector spaces with noncartesian bases are developed. Unlike the traditional group-theoretical approach, isomorphism is not the essential ingredient in crystallographic classification schemes. Because alternative classification schemes must be used, the notions of equivalence relations and classes which are fundamental to such schemes are defined, discussed and illustrated. For example, we will find that the classification of the crystallographic space groups into the traditional 230 types is defined in terms of their matrix representations. Therefore, the derivation of these groups from the point groups will be conducted using the 37 distinct matrix groups rather than the 32 point groups they represent.

Volume 14 of Reviews in Mineralogy covers a short course about the relations among the microscopic structure of minerals and their macroscopic thermodynamic properties. Understanding the micro-to-macro relations provides a rigorous theoretical foundation for formulation of energy relations. With such a foundation, measured parameters can be understood, and extrapolation and prediction of thermodynamic properties beyond the range of measurement can be done with more confidence than if only empirical relations are used.The purpose of this course is to consider the microscopic factors that influence the free energy of minerals: atomic environments, bonding, and crystal structure. These factors influence the structural energy and the detailed nature of the lattice vibrations which are an important source of entropy and enthalpy at temperatures greater than 0 K. The same factors determine the relative energy of different phases, and thereby; the relative stability of different minerals. Configurational entropy terms arising from disorder also contribute to the energy and entropy. In transition metal compounds there are additional energy and entropy terms arising from the electronic configurations, leading to additional stabilizations, magnetic ordering, and, incidentally, color.Organized by Sue Kieffer and Alex Navrotsky, the course was presented by the ten authors of this book on the campus of Washington College in Chestertown, Maryland. This was the second of MSA's short courses to be given in conjunction with meetings of the American Geophysical Union.

Volume 13 of Reviews in Mineralogy attempts to gather together much of our knowledge of micas, the most abundant phyllosilicate, and to indicate promising areas of future research. Chapters 1-3 lay the foundations of the classification, structures, and crystal chemistry of micas. Chapter 4 treats bonding and electrostatic modeling of micas. Chapters 5 and 6 cover spectroscopic and optical properties. Chapters 7-13, the bulk of the volume, are devoted to geochemistry and petrology. These include phase equilibria and the occurrences, chemistry, and petrology of micas in igneous, metamorphic, and sedimentary rocks, pegmatites, and certain ore deposits. Some treatments are exhaustive. All are at the forefront of our present knowledge, and indicate clearly the practical applications'of the study of micas to ascertaining various parameters of origin and crystallization history, as well as the many problems that still exist. The aim of this type of treatment is to provide a reference volume for teachers and students and to enable researchers to pick more easily those directions and problems for which future research is most needed or is apt to be most productive or most challenging.

Volume 2 of Reviews in Mineralogy displays the Short Course on Feldspar Mineralogy in Salt Lake City in October 1975. The workshops on x-ray single-crystal, powder diffraction methods and electron optical techniques as applied to the study of feldspars are the substance of which became the nine chapters of the first edition of Feldspar Mineralogy.It will be noted by readers experienced with feldspars that there are many new ideas appearing in Chapters 3, 4 and 5 that have neither received scrutiny by review (other than ourselves) nor survived practical tests of time in the research community. There is some danger in this, but the editor decided the greater risk was to produce a review volume soon to be outdated. Inevitably, given the different goals of individual authors in their assigned topics, some repetition of material has occurred, although usually with quite different emphases. Chapters 1, 2, 9 and 10, in which plagioclase structures and diffraction patterns and their Al,Si distributions, phase equilibria and exsolution textures are featured, are notable in this regard.

Volume 5 of Reviews in Mineralogy emphasizes the crystal chemistry and related physical properties of the major rock-forming orthosilicates. Though in some chapters more attention is given to phase equilibria and paragenesis than in others, these are for the most part cursorily treated with references to the more important papers and to review articles (also see Deer, Howie and Zussman, 1962, Rock-forming Minerals, Vol. 1, Ortho- and Ring Silicates).

Volume 10 of Reviews in Mineralogy reviews the use of a powerful probe into metamorphic process: mineral assemblages and the composition of minerals. Put very simply, this volume attempts to answer the question: "What can we learn about metamorphism through the study of minerals in metamorphic rocks?" It is not an encyclopedic summary of metamorphic mineral assemblages; instead it attempts to present basic research strategies and examples of their application. Moreover, in order to limit and unify the subject matter, it concentrates on the chemical aspects of metamorphism and regrettably ignores other important kinds of studies of metamorphic rocks and minerals conducted by structural geologists, structural petrologists, and geophysicists.

Volume 9B of Reviews in Mineralogy is dedicated more to an exploration of the social life of amphiboles and the amphibole personality in real rocks and in the experimental petrology laboratory. The chemical complexity of amphibole, which Robinson et al., refer to as "a mineralogical shark in a sea of unsuspecting elements," permits amphiboles to occur in a very wide variety of rock types, under a large range of pressure and temperature conditions, and in association with an impressive number of other minerals. The description of amphibole petrology and of petrologists' attempts to understand amphibole phase relations are therefore not simple matters, as the length of this volume suggests. Although they do not cover every type of amphibole occurrence, it is hoped that the papers in this volume will provide the amphibole student and researcher with an up-to-date summary of the most important aspects of amphibole petrology. Volume 9B, Amphiboles: Petrology and Experimental Phase Relations, was begun in 1981 in preparation for the Short Course on Amphiboles and Other Hydrous Pyriboles presented at Erlanger, Kentucky, October 29 - November 1, 1981, prior to the annual meetings of the Geological Society of America and associated societies. Unfortunately, only the first chapter was in manuscript form at the time of the short course, and publication was delayed by one year.

Most of Volume 9A of Reviews in Mineralogy treats amphiboles and other hydrous pyriboles as isolated systems. It reviews the structural complexity and resulting chemical variability and diversity of petrologic behavior of amphiboles, whereby Volume 9A contains a hefty dose of petrology and in contrast, Volume 9B is dedicated more to an exploration of the social life of amphiboles and the amphibole personality in real rocks and in the experimental petrology laboratory. This volume was prepared in conjunction with the Mineralogical Society of America Short Course on Amphiboles and Other Hydrous Pyriboles, Fall, 1981.

Volume 8 of Reviews in Mineralogy treats a Short Course in Kinetics, which brings together the fundamentals needed to explain field observations using kinetic data. It is hoped that this book may serve, not only as a reference for researchers dealing with the rates of geochemical processes, but also as a text in courses on geochemical kinetics. The book is organized with a rough temperature gradient in mind, i.e. low temperature kinetics at the beginning and igneous kinetics at the end. However, the topics in each chapter are general enough that they can be applied often to any geochemical domain: sedimentary, metamorphic or igneous. The theory of kinetics operates at two complementary levels: the phenomenological and the atomistic. The former relies on macroscopic variables (e.g. temperature or concentrations) to describe the rates of reactions or the rates of transport; the latter relates the rates to the basic forces operating between the particular atomic or molecular species of any system. This book deals with both descriptions of the kinetics of geochemical processes.

Volume 7 of Reviews in Mineralogy reviews the essential aspects of pyroxene research. Recently, Deer, Howie and Zussman (DHZ) published a second edition of their volume in the Rock-Forming Minerals series, Single-Chain Silicates, Vol. 2A (John Wiley, New York, 1978). The present volume is intended to be complementary to DHZ and to provide material covered lightly or not at all in DHZ, such as electron microscopy, spectroscopy, and detailed thermodynamic treatments. However, because the range of pyroxene research has grown so much in recent years, there still are important areas not covered comprehensively in either of these volumes. Some of these areas are kinetics, diffusion, crystal defects, deformation, and nonsilicate pyroxene crystal chemistry. Because of these omissions and because this volume is intended for use with the MSA Short Course on Pyroxenes to be held at Emory University in conjunction with the November, 1980 meeting of the Society, a Symposium on Pyroxenes was organized by J. Stephen Huebner for the meeting that is designed to present the latest research results on several different topics, including those above. With DHZ, this volume, and publications from the Symposium, the student of pyroxenes should be well-equipped to advance our knowledge of pyroxenes in the decades ahead.

Volume 6 of Reviews in Mineralogy was originated from notes prepared for a short course on Marine Minerals held in La Jolla, California, November 2-3, 1979. Chapters in this volume are devoted to marine manganese oxide, iron oxide, silica polymorphs, zeolite, clay, phosphorite, barite, evaporite, and placer minerals. Carbonates are not included; coverage of this important mineral group warrants a separate monograph. The extremely interesting sulfide and hydrothermal mineral assemblages recently discovered at oceanic spreading centers are also not discussed here. Marine Minerals was first published in 1979 as Volume 6 of the series entitled Short course. In 1980 the Mineralogical Society of America changed the name of the series to Reviews in Mineralogy, and for that reason this, the second printing of Marine Minerals has been reissued under the new banner. Only minor corrections have been made.

Volume 4 of Reviews in Mineralogy was prepared to serve as notes for a short course on the Mineralogy and Geology of Natural Zeolites held in Seattle, Washington, November 4-6, 1977. The title of the short course reads Natural Zeolites; however, the subject matter treated in the course and reviewed here deals primarily with those zeolites that occur in sedimentary rocks and which have formed by authigenic or burial diagenetic processes. Unfortunately, only limited coverage has been given to the classical occurrences of zeolites--the megascopic crystals in the vugs and cavities of basalts and other basic igneous rocks. Our only justification is that since the late 1950s, almost all major efforts on zeolites have been directed towards the "sedimentary" occurrences, and it is these occurrences of zeolites in sedimentary rocks that are still unfamiliar to many geologists and mineralogists. It is our intention that this short course and these notes will play a small role in alleviating this unfamiliarity.

Volume 60 of Reviews in Mineralogy and Geochemistry assesses the current state of knowledge of lunar geoscience, given the data sets provided by missions of the 1990's, and lists remaining key questions as well as new ones for future exploration to address. It documents how a planet or moon other than the world on which we live can be studied and understood in light of integrated suites of specific kinds of information. The Moon is the only body other than Earth for which we have material samples of known geologic context for study. This volume seeks to show how the different kinds of information gained about the Moon relate to each other and also to learn from this experience, thus allowing more efficient planning for the exploration of other worlds.

Volume 1 of Reviews in Mineralogy introduces to the mineralogy of sulfides. It covers the Determination, Relationships, and Classification of Sulfide Mineral Structures, Sulfide Crystal Chemistry, Electron Interactions and Chemical Bonding in Sulfides, Experimental Methods in Sulfide Synthesis, Sulfide Phase Equilibriaand Sulfide Petrology.The Short Course on Sulfide Mineralogy was given November 15-17, 1974, preceding the annual meetings of the affiliated societies of the Geological Society of America, at the Sheraton Four Ambassadors Hotel in Miami, Florida, USA with eighty persons in attendance.

Highly Siderophile and Strongly Chalcophile Elements in High Temperature Geochemistry and Cosmochemistry, Volume 81 This RiMG (Reviews in Mineralogy & Geochemistry) volume investigates the application of highly siderophile (HSE) and strongly chalcophile elements. This volume has its origin in a short course sponsored by the Mineralogical Society of America and the Geochemical Society held in San Diego, California on the 11th and 12th December 2015, ahead of the American Geophysical Union's Fall Meeting, which featured a session with the same title. Topics in this volume include: analytical methods and data quality experimental constraints applied to understanding HSE partitioning nucleosynthetic variations of siderophile and chalcophile elements HSE in the Earth, Moon, Mars and asteroidal bodies HSE and chalcophile elements in both cratonic and non-cratonic mantle, encompassing both sub-continental and sub-oceanic lithosphere the importance of the HSE for studying volcanic and magmatic processes, and an appraisal of the importance of magmatic HSE ore formation in Earth's crust. Highly siderophile and strongly chalcophile elements comprise Re, Os, Ir, Ru, Pt, Rh, Pd, Au, Te, Se and S and are defined by their strong partitioning into the metallic phase, but will also strongly partition into sulfide phases, in the absence of metal. The chemical properties of the HSE mean that they are excellent tracers of key processes in high temperature geochemistry and cosmochemistry, having applications in virtually all areas of earth science. A key aspect of the HSE is that three long-lived, geologically useful decay systems exist with the HSE as parent (107Pd-107Ag), or parent-daughter isotopes (187Re-187Os and 190Pt-186Os). The material in this book is accessible for graduate students, researchers, and professionals with interests in the geochemistry and cosmochemistry of these elements, geochronology, magmatic ore bodies and the petrogenesis of platinum-group minerals.

Petrochronology is a rapidly emerging branch of Earth science that links time (ages or rates) with specific rock-forming processes and their physical conditions. It is founded in petrology and geochemistry, which define a petrogenetic context or delimit a specific process, to which chronometric data are then linked. This combination informs Earth's petrogenetic processes better than petrology or geochronology alone. This volume and the accompanying short courses address three broad categories of inquiry.　Conceptual approaches chapters　include petrologic modeling of multi-component chemical and mineralogic systems, and development of methods that include diffusive alteration of mineral chemistry.　Methods chapters　address four main analytical techniques, specifically EPMA, LA-ICP-MS, SIMS and TIMS.　Mineral-specific chapters　explore applications to a wide range of minerals, including zircon (metamorphic, igneous, and detrital/Hadean), baddeleyite, REE minerals (monazite, allanite, xenotime and apatite), titanite, rutile, garnet, and major igneous minerals (olivine, plagioclase and pyroxenes). These applications mainly focus on metamorphic, igneous, or tectonic processes, but additionally elucidate fundamental transdisciplinary progress in addressing mechanisms of crystal growth, the chemical consequences of mineral growth kinetics, and how chemical transport and deformation affect chemically complex mineral composites. Most chapters further recommend areas of future research.

Volume 12 of Reviews in Mineralogy introduces to fluid inclusions. It covers the folowing questions: when and where inclusions form. how they change, how to prepare material and make microthermometric measurementsl, how to interpret these data, and what has been found in applications of fluid-inclusion studies to each of a series of different geologic environments. This book also attempts to discuss the many applications of fluid inclusions to the study of and understanding of geologic processes and the geologic environments in which they acted.

Volume 11 of Reviews in Mineralogy attempts to synthesize our present understanding of certain aspects of the mineralogy and chemistry of the rock-forming carbonates. This review follows, by ten years, a major assessment of (sedimentary) carbonate minerals by Lippmann (1973). There is only minor overlap of subject material, and I hope that this difference reflects fairly how this field has developed.In this volume, some of the papers are general (i.e., those addressing crystal chemistry and phase relations), and they provide overviews of a fundamental nature and are of interest to many. Others are more specialized in coverage and generally reflect the different approaches used in carbonate geochemistry. The final chapter introduces transmission electron microscopy, a relatively new and powerful technique for mineralogical research that has great potential in carbonate research.

Volume 45 of Reviews in Mineralogy and Geochemistry is a new and expanded update of Volume 4 from 1977. Most of the material in this volume is entirely new, and Natural Zeolites: Occurrence, Properties, Applications presents a fresh and expanded look at many of the subjects contained in Volume 4.There has been an explosion in our knowledge of the crystal chemistry and structures of natural zeolites (Chapters 1 and 2), due in part to the now-common Rietveld method that allows treatment of powder diffraction data. Studies on the geochemistry of natural zeolites have also greatly increased, partly as a result of the interests related to the disposal of radioactive wastes, and Chapters 3, 4, 5, 13, and 14 detail the latest results in this important area. Until the latter part of the 20th century, zeolites were often looked upon as a geological curiosity, but they are now known to be widespread throughout the world in sedimentary and igneous deposits and in soils (Chapters 6-12). The application of natural zeolites has greatly expanded since the first zeolite volume. Chapter 15 details the use of natural zeolites for removal of ammonium ions, heavy metals, radioactive cations, and organic molecules from natural waters, wastewaters, and soils. Similarly, Chapter 16 describes the use of natural zeolites as building blocks and cements in the building industry, Chapter 17 outlines their use in solar energy storage, heating, and cooling applications, and Chapter 18 describes their use in a variety of agricultural applications, including as soil conditioners, slow-release fertilizers, soil-less substrates, carriers for insecticides and pesticides, and remediation agents in contaminated soils.

Volume 64 of Reviews in Mineralogy and Geochemistry presents examples that include the effects of inhaled dust particles in the lung (Huang et al. 2006; Schoonen et al. 2006), biomineralization of bones and teeth (Glimcher et al. 2006), the formation of kidney-stones, the calcification of arteries, the speciation exposure pathways and pathological effects of heavy metal contaminants (Reeder et al. 2006; Plumlee et al. 2006), the transport and fate of prions and pathological viruses in the environment (Schramm et al. 2006), the possible environmental-genetic link in the occurrence of neurodegenerative diseases (Perl and Moalem 2006), the design of biocompatible, bioactive ceramics for use as orthopaedic and dental implants and related tissue engineering applications (Cerruti and Sahai 2006) and the use of oxide-encapsulated living cells for the development of biosensors (Livage and Coradin 2006).

Volume 63 of Reviews in Mineralogy and Geochemistry provides an introduction for those not yet familiar with neutrons by describing basic features of neutrons and their interaction with matter as well illustrating important applications. The volume is divided into 17 Chapters. The first two chapters introduce properties of neutrons and neutron facilities, setting the stage for applications. Some applications rely on single crystals (Chapter 3) but mostly powders (Chapters 4-5) and bulk polycrystals (Chapters 15-16) are analyzed, at ambient conditions as well as low and high temperature and high pressure (Chapters 7-9). Characterization of magnetic structures remains a core application of neutron scattering (Chapter 6). The analysis of neutron data is not trivial and crystallographic methods have been modified to take account of the complexities, such as the Rietveld technique (Chapter 4) and the pair distribution function (Chapter 11). Information is not only obtained about solids but about liquids, melts and aqueous solutions as well (Chapters 11-13). In fact this field, approached with inelastic scattering (Chapter 10) and small angle scattering (Chapter 13) is opening unprecedented opportunities for earth sciences. Small angle scattering also contributes information about microstructures (Chapter 14). Neutron diffraction has become a favorite method to quantify residual stresses in deformed materials (Chapter 16) as well as preferred orientation patterns (Chapter 15). The volume concludes with a short introduction into neutron tomography and radiography that may well emerge as a principal application of neutron scattering in the future (Chapter 17).

Volume 38 of Reviews in Mineralogy provides detailed reviews of various aspects of the mineralogy and geochemistry of uranium. We have attempted to produce a volume that incorporates most important aspects of uranium in natural systems, while providing some insight into important applications of uranium mineralogy and geochemistry to environmental problems. The result is a blend of perspectives and themes: historical (Chapter 1), crystal structures (Chapter 2), systematic mineralogy and paragenesis (Chapters 3 and 7), the genesis of uranium ore deposits (Chapters 4 and 6), the geochemical behavior of uranium and other actinides in natural fluids (Chapter 5), environmental aspects of uranium such as microbial effects, groundwater contamination and disposal of nuclear waste (Chapters 8, 9 and 10), and various analytical techniques applied to uranium-bearing phases (Chapters 11-14).This volume was written in preparation for a short course by the same title, sponsored by the Mineralogical Society of America, October 22 and 23, 1999 in Golden, Colorado, prior to MSA's joint annual meeting with the Geological Society of America.

Volume 21 of Reviews in Mineralogy treats a short course on the rare earth elements to about 80 participants in San Francisco, California, December 1-3, 1989, just prior to the fall meeting of the American Geophysical Union. Contents:Cosmochemistry of the Rare Earth Elements: Condensation and Evaporation ProcessesRadiogenic Isotope Geochemistry of Rare Earth ElementsPartitioning of Rare Earth Elements between Major Silicate Minerals and Basaltic MeltsAn Approach to Trace Element Modeling Using a Simple Igneous System as an ExampleRare Earth Elements in Upper Mantle RocksRare Earth Elements in Metamorphic RocksRare Earth Elements in Sedimentary Rocks: Influence of Provenance and Sedimentary ProcessesAqueous Geochemistry of Rare Earth ElementsRare Earth Elements in Lunar MaterialsCompositional and Phase Relations among Rare Earth Element MineralsEconomic Geology of Rare Earth MineralsCathodoluminescence Emission Spectra of Rare Earth Element Activators in Minerals

Volume 43 of Reviews in Mineralogy and Geochemistry follows the 1986 Reviews in Mineralogy (Vol. 16) in approach but reflects significant changes in the field of Stable Isotope Geochemistry. In terms of new technology, new sub-disciplines, and numbers of researchers, the field has changed more in the past decade than in any other since that of its birth. Unlike the 1986 volume, which was restricted to high temperature fields, this book covers a wider range of disciplines. However, it would not be possible to fit a comprehensive review into a single volume. Our goal is to provide state-of-the-art reviews in chosen subjects that have emerged or advanced greatly since 1986. This volume was prepared for Short Course on Stable Isotope Geochemistry presented November 2-4, 2001 in conjunction with the annual meetings of the Geological Society of America in Boston, Massachusetts.